Author: Ignacio Rojas

0000000001317380

AUTHOR

Ignacio Rojas

Structural and magnetic characterization of the tridimensional network [Fe(HCO2)3]n·nHCO2H

In this work we report the structural and magnetic characterization of a new three-dimensional porous metal–organic framework (MOF) based on iron(III) and the formate anion, [Fe(HCO2)3]n·nHCO2H (1), which was obtained by solvothermal synthesis. The tridimensional structure crystallizes in the trigonal space group Rc and is formed by highly regular octahedral Fe(OHCO)6 units. These units contain six equal Fe–O distances, with angles slightly different from 90° or 180°. The packing of 1 corresponds to a 3D covalent network defined by face sharing between the parallelepipeds, which are formed by the interactions of Fe(OHCO)6 units through formate ligands, thus generating a 41263 topology. This…

research product

CCDC 915782: Experimental Crystal Structure Determination

Related Article: Verónica Paredes-García, Ignacio Rojas, Rosa Madrid, Andres Vega, Efrén Navarro-Moratalla, Walter Cañón-Mancisidor, Evgenia Spodine, Diego Venegas-Yazigi|2013|New J.Chem.|37|2120|doi:10.1039/C3NJ00023K

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PEPhysical Sciences and Engineering
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