0000000001317385

AUTHOR

Pablo Martín-ramos

showing 2 related works from this author

Coordinating and hydrogen bonding ability of a bifunctional 2D paddle-wheel copper(II) coordination polymer

2015

abstract A new copper(II) complex of formula {[Cu 2 (H 2 btc) 2 (dmf) 2 ] 4dmf} n (1)[H 4 btc = 1,2,4,5-benzenetetracarb-oxylic acid, dmf = dimethylformamide] has been synthesised and its structure determined by X-raydiffraction. The structure displays a new square grid of ‘‘paddle-wheel’’ tetracarboxylate-bridgeddicopper(II) units with an intradimer copper–copper separation of 2.619(2) A. The dmf molecules areretained through weak axial coordinative bonds and hydrogen bonding interactions with the carboxylicgroups of the porous neutral network of 4 4 net topology. The magnetic behaviour of 1 corresponds to astrong antiferromagnetic coupling within each dicopper(II) unit (J = 343 cm 1 with …

ChemistryHydrogen bondLigandCoordination polymerInorganic chemistryCrystal engineeringInorganic Chemistrychemistry.chemical_compoundCrystallographyPaddle wheelMaterials ChemistryMoleculeCarboxylatePhysical and Theoretical ChemistryBifunctionalPolyhedron
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CCDC 891353: Experimental Crystal Structure Determination

2014

Related Article: Consuelo Yuste-Vivas, Manuela Ramos Silva, Pablo Martín-Ramos, Laura C.J. Pereira, Jesús Ferrando-Soria, Pedro Amorós, Miguel Julve|2015|Polyhedron|87|220|doi:10.1016/j.poly.2014.11.026

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-25-dicarboxyterephthalato)-bis(NN-dimethylformamide)-di-copper(ii) NN-dimethylformamide solvate]Crystal StructureCell ParametersExperimental 3D Coordinates
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