0000000001317605

AUTHOR

C.v. Rani

showing 3 related works from this author

Bis{3,5-di-tert-butyl-N-[(4-dimethylamino)phenyl]salicylaldiminato}cobalt(II)

2017

In the title complex [systematic name: bis(2,4-di-tert-butyl-6-{N-[4-(dimethylamino)phenyl]carboximidoyl}phenolato)cobalt(II)], [Co(C23H31N2O)2], the cobalt(II) atom is coordinated by pairs of O and N atoms in a distorted tetrahedral coordination geometry. The dihedral angles formed by the aromatic rings of the same ligand are 51.99 (11) and 36.58 (9)°. The molecular conformation features weak intramolecular C—H...O hydrogen bonds. In the crystal, inversion-related pairs of complex molecules are linked into dimers by weak C—H...π interactions. The methyl C atoms oftert-butyl groups have rotational disorder, with site occupancies of 0.647 (7) and 0.617 (6) for the major components and 0.353 …

crystal structureHydrogen bondLigandchemistry.chemical_elementAromaticityCrystal structureDihedral angle010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencescobalt(II) complex0104 chemical sciencesCrystalCrystallographychemistrylcsh:QD901-999lcsh:Crystallographydistorted tetrahedral geometryCobaltCoordination geometryIUCrData
researchProduct

CCDC 1542611: Experimental Crystal Structure Determination

2017

Related Article: C.V. Rani, L. Mitu, G. Chakkaravarthi, G. Rajagopal|2017|IUCrData|2|x170525|doi:10.1107/S2414314617005259

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersBis(35-di-t-butyl-N-[(4-dimethylamino)phenyl]salicylaldiminato)-cobalt(ii)Experimental 3D Coordinates
researchProduct

CCDC 1552570: Experimental Crystal Structure Determination

2017

Related Article: C.V. Rani, L. Mitu, G. Chakkaravarthi, G. Rajagopal|2017|IUCrData|2|x170784|doi:10.1107/S2414314617007842

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(24-di-t-butyl-6-({[4-(diethylamino)phenyl]imino}methyl)phenolato)-cobalt(ii) unknown solvateExperimental 3D Coordinates
researchProduct