Author: Junjun Ba

0000000001317756

AUTHOR

Junjun Ba

showing 3 related works from this author

Constrained formation of 2-(1-(arylimino)ethyl)-7-arylimino-6,6-dimethylcyclopentapyridines and their cobalt(ii) chloride complexes: synthesis, chara…

2015

A series of 2-(1-(arylimino)ethyl)-7-arylimino-6,6-dimethylcyclopentapyridine derivatives (L1-L5) was synthesized, and individually reacted with cobalt(II) chloride to form the corresponding cobalt chloride complexes (C1-C4). These compounds were characterized, and the single crystal X-ray diffraction for two representative cobalt complexes was carried out. The molecular structures indicate that 2,7-bis(arylimino)cyclopentapyridines act as tridentate ligands; however, one of the Co-N coordinative bonds is weak due to the spatial separation of nitrogen atoms. Upon activation with either MAO or MMAO, all cobalt complexes exhibit catalytic activities toward ethylene. Polymerization takes place…

Ethylene010405 organic chemistryGeneral Chemical EngineeringInorganic chemistrychemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesChlorideNitrogen0104 chemical sciencesCatalysisCobalt(II) chloridechemistry.chemical_compoundPolymerizationchemistryPolymer chemistrymedicineCobaltSingle crystalmedicine.drugRSC Advances

researchProduct

CCDC 1054235: Experimental Crystal Structure Determination

2015

Related Article: Junjun Ba, Shizhen Du, Erlin Yue, Xinquan Hu, Zygmunt Flisak, Wen-Hua Sun|2015|RSC Advances|5|32720|doi:10.1039/C5RA04722F

Space GroupCrystallographyCrystal SystemDichloro-(N-(26-diethylphenyl)-2-(1-((26-diethylphenyl)imino)ethyl)-66-dimethyl-56-dihydro-7H-cyclopenta[b]pyridin-7-imine)-cobalt unknown solvateCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1054234: Experimental Crystal Structure Determination

2015

Related Article: Junjun Ba, Shizhen Du, Erlin Yue, Xinquan Hu, Zygmunt Flisak, Wen-Hua Sun|2015|RSC Advances|5|32720|doi:10.1039/C5RA04722F

Space GroupCrystallographyDichloro-(N-(26-dimethylphenyl)-2-(1-((26-dimethylphenyl)imino)ethyl)-66-dimethyl-56-dihydro-7H-cyclopenta[b]pyridin-7-imine)-cobalt(ii) unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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