Author: María Frutos

0000000001317830

AUTHOR

María Frutos

showing 4 related works from this author

Triazole vs. triazolium carbene ligands in the site-selective cyclometallation of o-carboranes by M(iii) (M = Ir, Rh) complexes

2018

Ir(iii) and Rh(iii)-mediated site-selective cage B-H and C-H bond activation in o-carboranylmethyl derivatives has been achieved. The selectivity of the reaction is related to the electron donating properties of the ligand. 1,2,3-Triazole-derivatives use the N2 position of the triazole ring to direct the selective o-carborane B-H bond activation, whereas the corresponding triazolylidene derivatives lead to the cage C-H bond activation with complete site-selectivity.

010405 organic chemistryLigandTriazole010402 general chemistryRing (chemistry)01 natural sciencesMedicinal chemistry0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistrySite selectiveSelectivityCarbeneDalton Transactions

researchProduct

CCDC 1824868: Experimental Crystal Structure Determination

2018

Related Article: María Frutos, Mar Gómez-Gallego, Elena A. Giner, Miguel A. Sierra, Carmen Ramírez de Arellano|2018|Dalton Trans.|47|9975|doi:10.1039/C8DT02296H

Space GroupCrystallography(2-(4-ferrocenyl-123-triazol-1-ylmethyl)-12-dicarba-closo-dodecaborane)-chloro-(pentamethyl-cyclopentadienyl)-iridiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1824870: Experimental Crystal Structure Determination

2018

Related Article: María Frutos, Mar Gómez-Gallego, Elena A. Giner, Miguel A. Sierra, Carmen Ramírez de Arellano|2018|Dalton Trans.|47|9975|doi:10.1039/C8DT02296H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-(3-methyl-4-phenyl-123-triazol-3-ium-5-yl-1-ylmethyl)-12-dicarba-closo-dodecaboranyl)-chloro-(pentamethyl-cyclopentadienyl)-iridiumExperimental 3D Coordinates

researchProduct

CCDC 1824869: Experimental Crystal Structure Determination

2018

Related Article: María Frutos, Mar Gómez-Gallego, Elena A. Giner, Miguel A. Sierra, Carmen Ramírez de Arellano|2018|Dalton Trans.|47|9975|doi:10.1039/C8DT02296H

(1-(3-methyl-4-phenyl-123-triazol-3-ium-15-diyl)-12-dicarba-closo-dodecaborane(11))-chloro-gold(i)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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