0000000001318070

AUTHOR

Animesh Pradhan

showing 2 related works from this author

Mixed phenoxo and azido bridged dinuclear nickel(II) and copper(II) compounds with N,N,O-donor schiff bases: Synthesis, structure, DNA binding, DFT a…

2019

Abstract Two dinuclear complexes, µ-phenoxo, µ1,1-azido bridged [Ni2(L)2(µ1,1-N3)(N3)(CH3OH)] (1) and µ-phenoxo, µ1,1-azido bridged [Cu2(L)2(µ1,1-N3)(N3)] (2) bearing HL as a blocking co-ligand produced by the 1:1 condensation of N-methyl 1,3 propanediamine with o-vanillin have been synthesized and successfully characterized by elemental analyses, IR and electronic spectroscopy, single-crystal X-ray diffraction for 1 and DFT optimization for 2. X-ray crystal structure discloses that the asymmetric unit of 1 consists of two nickel(II) ions exhibiting a six-coordinate octahedral coordination with µ-phenoxo, µ1,1-azido bridging dimeric structure. The DFT optimization of 2 reveals the five-coor…

010405 organic chemistryChemistrychemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciencesFluorescenceCopperElectron spectroscopySquare pyramidal molecular geometry0104 chemical sciencesInorganic ChemistryNickelCrystallographyOctahedronDocking (molecular)Materials ChemistryPhysical and Theoretical ChemistryInorganica Chimica Acta
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CCDC 1501314: Experimental Crystal Structure Determination

2017

Related Article: Animesh Pradhan, Shobhraj Haldar, Krishnasis Basu Mallik, Mrinmoy Ghosh, Manindranath Bera, Nayim Sepay, Dieter Schollmeyer, Sumanta Kumar Ghatak, Sanchita Roy, Sandip Saha|2019|Inorg.Chim.Acta|484|197|doi:10.1016/j.ica.2018.09.026

Space GroupCrystallographyCrystal SystemCrystal Structure(mu-azide)-(azide)-(methanol)-[2-methoxy-6-({[3-(methylamino)propyl]imino}methyl)phenolato]-{mu-[2-({[3-(methylamino)propyl]imino}methyl)-6-(methoxy)phenolato]}-di-nickel(ii)Cell ParametersExperimental 3D Coordinates
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