0000000001318070
AUTHOR
Animesh Pradhan
Mixed phenoxo and azido bridged dinuclear nickel(II) and copper(II) compounds with N,N,O-donor schiff bases: Synthesis, structure, DNA binding, DFT and molecular docking study
Abstract Two dinuclear complexes, µ-phenoxo, µ1,1-azido bridged [Ni2(L)2(µ1,1-N3)(N3)(CH3OH)] (1) and µ-phenoxo, µ1,1-azido bridged [Cu2(L)2(µ1,1-N3)(N3)] (2) bearing HL as a blocking co-ligand produced by the 1:1 condensation of N-methyl 1,3 propanediamine with o-vanillin have been synthesized and successfully characterized by elemental analyses, IR and electronic spectroscopy, single-crystal X-ray diffraction for 1 and DFT optimization for 2. X-ray crystal structure discloses that the asymmetric unit of 1 consists of two nickel(II) ions exhibiting a six-coordinate octahedral coordination with µ-phenoxo, µ1,1-azido bridging dimeric structure. The DFT optimization of 2 reveals the five-coor…
CCDC 1501314: Experimental Crystal Structure Determination
Related Article: Animesh Pradhan, Shobhraj Haldar, Krishnasis Basu Mallik, Mrinmoy Ghosh, Manindranath Bera, Nayim Sepay, Dieter Schollmeyer, Sumanta Kumar Ghatak, Sanchita Roy, Sandip Saha|2019|Inorg.Chim.Acta|484|197|doi:10.1016/j.ica.2018.09.026