0000000001318074
AUTHOR
Selma Dhifaoui
New insights on the electronic, magnetic, electric and molecular structure of a bis-(4-cyanopyridine) iron(III) complex with the meso-tetrakis(4-methoxyphenyl)porphyrin
International audience; We have successfully synthesized and characterized a new low-spin iron(III) bis(4-cyanopyridine) complex with a meso-porphyrin substituted in the para positions of the phenyls by the methoxy group, namely the bis(4-cyanopyridine)[(meso-tetrakis(4-metoxyphenylporphyrinato)]iron(III) trifluoromethanesulfonate chlorobenzene monosolvate complex with the formula [FeIII(TMPP)(4-CNpy)2]SO3CF3.C6H5Cl (I). This species was characterized through ultraviolet–visible, Fourier-transform infrared and Mössbauer spectroscopy as well as by SQUID magnetometry, cyclic voltammetry, and X-ray crystallography. These characterizations indicated that our synthetic heme model is a low-spin (…
CCDC 975958: Experimental Crystal Structure Determination
Related Article: Leila Ben Haj Hassen, Selma Dhifaoui, Yoann Rousselin, Valérie Marvaud, Christine Stern, Charles E. Schulz, Habib Nasri|2019|Inorg.Chim.Acta|486|675|doi:10.1016/j.ica.2018.11.040