0000000001318076
AUTHOR
Dina V. Boyarskaya
Syntheses and Structures of a Series of Acyclic Diaminocarbene Palladium(II) Complexes Derived from 3,4-Diaryl-1H-pyrrol-2,5-diimines and Bisisocyanide Palladium(II) Complexes
Reactions of 3,4-diaryl-1H-pyrrol-2,5-diimines with various bisisocyanide palladium(II) complexes were studied. The coupling proceeds with one isocyanide ligand to accomplish the acyclic diaminocarbene complexes. The structure of generated diaminocarbene complexes depends on bulkiness of isocyanide ligand in the bisisocyanide complexes of palladium(II). The imino-group of 3,4-diaryl-1H-pyrrol-2,5-diimine reacts with one isocyanide ligand of cis-[PdCl2(CN–R)2] (R = i-Pr, Cy, t-Bu, Bn), and the nitrogen atom of the pyrrole ring is coordinated to the palladium center as the second isocyanide ligand remains intact. In the case of cis-[PdCl2(CN–R)2] (R = 2-acyloxyphenyl, 2-sulfonyloxyphenyl), on…
2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate
In the title compound, C16H11NO2·C5H9NO, the dihedral angles between the maleimide and phenyl rings are 34.7 (2) and 64.8 (2)°. In the crystal, the 2,3-diphenylmaleimide and 1-methylpyrrolidin-2-one molecules form centrosymmetrical dimersviapairs of strong N—H...O hydrogen bonds and π–π stacking interactions between the two neighboring maleimide rings [centroid–centroid distance = 3.495 (2) Å]. The dimers are further linked by weak C—H...O and C—H...π hydrogen bonds into a three-dimensional framework.
CCDC 1817631: Experimental Crystal Structure Determination
Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725
CCDC 1818370: Experimental Crystal Structure Determination
Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725
CCDC 1817212: Experimental Crystal Structure Determination
Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725
CCDC 1822187: Experimental Crystal Structure Determination
Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725