0000000001318785

AUTHOR

Michael R. Reynolds

showing 3 related works from this author

Halogen bonding and host–guest chemistry between N-alkylammonium resorcinarene halides, diiodoperfluorobutane and neutral guests

2019

Single crystal X-ray structures of halogen-bonded assemblies formed between host N-hexylammonium resorcinarene bromide (1) or N-cyclohexylammonium resorcinarene chloride (2), and 1,4-diiodooctafluorobutane and accompanying small solvent guests (methanol, acetonitrile and water) are presented. The guests’ inclusion affects the geometry of the cavity of the receptors 1 and 2, while the divalent halogen bond donor 1,4-diiodooctafluorobutane determines the overall nature of the halogen bond assembly. The crystal lattice of 1 contains two structurally different dimeric assemblies A and B, formally resulting in the mixture of a capsular dimer and a dimeric pseudo-capsule. 1H and 19F NMR analyses …

inorganic chemicalscapsuleDimerHalideFluorine-19 NMRCrystal structurelcsh:QD241-441kemialliset sidoksetchemistry.chemical_compoundlcsh:Organic chemistryBromidesupramolekulaarinen kemiahost-guest chemistryhost–guest chemistrylcsh:ScienceHost–guest chemistryta116Biochemistry Biophysics and Structural BiologyX-ray crystallographyresorcinarene saltsHalogen bondChemistryOrganic ChemistryResorcinareneChemistryCrystallographyhalogen bondinglcsh:Qröntgenkristallografiadimeric assembliesBeilstein Journal of Organic Chemistry
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CCDC 1894767: Experimental Crystal Structure Determination

2019

Related Article: Fangfang Pan, Mohadeseh Dashti, Michael R. Reynolds, Kari Rissanen, John F. Trant, Ngong Kodiah Beyeh|2019|Beilstein J.Org.Chem.|15|947|doi:10.3762/bjoc.15.91

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersNN'N''N'''-{[46101216182224-octahydroxy-281420-tetrapropylpentacyclo[19.3.1.137.1913.11519]octacosa-1(25)3(28)469(27)101215(26)16182123-dodecaene-5111723-tetrayl]tetrakis(methylene)}tetracyclohexanaminium tetrachloride bis(11223344-octafluoro-14-di-iodobutane) dihydrateExperimental 3D Coordinates
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CCDC 1894766: Experimental Crystal Structure Determination

2019

Related Article: Fangfang Pan, Mohadeseh Dashti, Michael R. Reynolds, Kari Rissanen, John F. Trant, Ngong Kodiah Beyeh|2019|Beilstein J.Org.Chem.|15|947|doi:10.3762/bjoc.15.91

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersNN'N''N'''-{[46101216182224-octahydroxy-281420-tetrapropylpentacyclo[19.3.1.137.1913.11519]octacosa-1(25)3(28)469(27)101215(26)16182123-dodecaene-5111723-tetrayl]tetrakis(methylene)}tetrakis(hexan-1-aminium) tetrabromide 11223344-octafluoro-14-diiodobutane acetonitrile methanol solvateExperimental 3D Coordinates
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