Author: Joseph M. Sperling

0000000001319049

AUTHOR

Joseph M. Sperling

Understanding the Stabilization and Tunability of Divalent Europium 2.2.2B Cryptates

Lanthanides such as europium with more accessible divalent states are useful for studying redox stability afforded by macrocyclic organic ligands. Substituted cryptands, such as 2.2.2B cryptand, that increase the oxidative stability of divalent europium also provide coordination environments that support synthetic alterations of Eu(II) cryptate complexes. Two single crystal structures were obtained containing nine-coordinate Eu(II) 2.2.2B cryptate complexes that differ by a single coordination site, the occupation of which is dictated by changes in reaction conditions. A crystal structure containing a [Eu(2.2.2B)Cl]+ complex is obtained from a methanol-THF solvent mixture, while a methanol-…

research product

CCDC 2057854: Experimental Crystal Structure Determination

Related Article: Todd N. Poe, Maria J. Beltra��n-Leiva, Cristian Celis-Barros, William L. Nelson, Joseph M. Sperling, Ryan E. Baumbach, Harry Ramanantoanina, Manfred Speldrich, Thomas E. Albrecht-Scho��nzart|2021|Inorg.Chem.|60|7815|doi:10.1021/acs.inorgchem.1c00300

research product

CCDC 2057855: Experimental Crystal Structure Determination

Related Article: Todd N. Poe, Maria J. Beltra��n-Leiva, Cristian Celis-Barros, William L. Nelson, Joseph M. Sperling, Ryan E. Baumbach, Harry Ramanantoanina, Manfred Speldrich, Thomas E. Albrecht-Scho��nzart|2021|Inorg.Chem.|60|7815|doi:10.1021/acs.inorgchem.1c00300

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PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
  - PE2_1Theory of fundamental interactions
  - PE2_2 Phenomenology of fundamental interactions
  - PE2_3Experimental particle physics with accelerators
  - PE2_4Experimental particle physics without accelerators
  - PE2_6Nuclear, hadron and heavy ion physics
  - PE2_8Gas and plasma physics
  - PE2_5Classical and quantum physics of gravitational interactions
  - PE2_7Nuclear and particle astrophysics
  - PE2_9 Electromagnetism
  - PE2_10Atomic, molecular physics
  - PE2_11Ultra-cold atoms and molecules
  - PE2_18Equilibrium and non-equilibrium statistical mechanics: steady states and dynamics
  - PE2_14Lasers, ultra-short lasers and laser physics
  - PE2_17Metrology and measurement
  - PE2_16Non-linear physics
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  - PE2_13Quantum optics and quantum information
  - PE2_15Thermodynamics
- PE1Mathematics
  - PE1_1Logic and foundations
  - PE1_6Geometry and global analysis
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  - PE1_15Generic statistical methodology and modelling
  - PE1_4 Algebraic and complex geometry
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  - PE1_5Lie groups, Lie algebras
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- PE3Condensed Matter Physics
  - PE3_1Structure of solids, material growth and characterisation
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  - PE11_1Engineering of biomaterials, biomimetic, bioinspired and bio-enabled materials
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  - PE11_4Engineering of polymers and plastics
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  - PE11_6Engineering of carbon materials
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  - PE11_8Engineering of alternative established or emergent materials
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  - PE11_11Porous materials engineering, e.g. covalent-organic, metal-organic, porous aromatic frameworks
  - PE11_12Semi-conducting and magnetic materials engineering
  - PE11_13Metamaterials engineering
  - PE11_14Computational methods for materials engineering
LSLife Sciences
- LS1Molecules of Life: Biological Mechanisms, Structures and Functions
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- LS2Integrative Biology: from Genes and Genomes to Systems
  - LS2_1Genetics
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  - LS2_2Gene editing
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  - LS2_7Transcriptomics
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  - LS2_11Bioinformatics and computational biology
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  - LS2_16Innovative methods and modelling in integrative biology
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  - LS4_1Organ and tissue physiology and pathophysiology
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  - LS4_3Physiology of ageing
  - LS4_2Comparative physiology
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  - LS4_6Microbiome and host physiology
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  - LS4_10The cardiovascular system and cardiovascular diseases
  - LS4_11Haematopoiesis and blood diseases
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  - LS4_13Other non-communicable diseases (except disorders of the nervous system and immunity-related diseases)
- LS3Cell Biology, Development, Stem Cells and Regeneration
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  - LS3_6Organelle biology and trafficking
  - LS3_7Mechanobiology of cells, tissues and organs
  - LS3_8Embryogenesis, pattern formation, morphogenesis
  - LS3_9Cell differentiation, formation of tissues and organs
  - LS3_10Developmental genetics
  - LS3_11Evolution of developmental strategies
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  - LS3_3Cell behaviour, including control of cell shape, cell migration
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- LS5Neuroscience and Disorders of the Nervous System
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  - LS5_16Systems and computational neuroscience (e.g. modelling, simulation, brain oscillations, connectomics)
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SHSocial Sciences and Humanities
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