Author: Bastian Dumslaff

0000000001319233

AUTHOR

Bastian Dumslaff

A Phenylene-Bridged Cyclohexa-meta-phenylene as Hexa-peri-hexabenzocoronene Precursor.

A phenylene-bridged cyclohexa-meta-phenylene was synthesized via intramolecular Yamamoto coupling of an appropriate p-quinquephenyl derivative carrying four m-chlorophenyl substituents. The structural proof could be obtained by single-crystal X-ray diffraction analysis, which also revealed a slightly strained structure with an internal phenylene bridge. Notably, this cyclo-meta-phenylene served as a novel precursor for hexa-peri-hexabenzocoronene (HBC). The cyclodehydrogenation proceeded smoothly, providing the corresponding HBC derivative as confirmed by MALDI-TOF-MS, and UV/Vis spectroscopy.

research product

CCDC 1837456: Experimental Crystal Structure Determination

Related Article: Bastian Dumslaff, Manfred Wagner, Dieter Schollmeyer, Akimitsu Narita, Klaus Müllen|2018|Chem.-Eur.J.|24|11908|doi:10.1002/chem.201801949

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