0000000001319239
AUTHOR
Nael Abutaha
Synthesis, structure and in vitro anticancer activity of Pd(II) complexes of mono- and bis-pyrazolyl-s-triazine ligands
Abstract The square planar complexes [Pd(MPT)Cl2] (1) and [Pd(BPT)Cl]ClO4 (2) were synthesized by the reaction of the 4,4′-(6-(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazine-2,4-diyl)dimorpholine (MPT) and N-methyl-N-phenyl-4,6-di(1H-pyrazol-1-yl)-1,3,5-triazin-2-amine (BPT) ligands with PdCl2 (1:1) in acetone under thermal conditions, respectively. In complex 1, the Pd(II) ion is coordinated with the MPT ligand as a bidentate NN-chelate, augmented with two chloride ligands in cis positions. In complex 2, the Pd(II) ion is coordinated with the BPT ligand as a tridentate N-chelate in a pincer fashion, together with one chloride ligand. Hirshfeld analysis indicated that complex 1 is packed with…
CCDC 1998456: Experimental Crystal Structure Determination
Related Article: Jamal Lasri, Hessa H. Al-Rasheed, Ayman El-Faham, Matti Haukka, Nael Abutaha, Saied M. Soliman|2020|Polyhedron|187|114665|doi:10.1016/j.poly.2020.114665
CCDC 1998457: Experimental Crystal Structure Determination
Related Article: Jamal Lasri, Hessa H. Al-Rasheed, Ayman El-Faham, Matti Haukka, Nael Abutaha, Saied M. Soliman|2020|Polyhedron|187|114665|doi:10.1016/j.poly.2020.114665