0000000001319422

AUTHOR

Cheng Du

showing 2 related works from this author

Single Crystal Sub‐Nanometer Sized Cu6(SR)6 Clusters: Structure, Photophysical Properties, and Electrochemical Sensing

2016

Organic ligand-protected metal nanoclusters have attracted extensively attention owing to their atomically precise composition, determined atom-packing structure and the fascinating properties and promising applications. To date, most research has been focused on thiol-stabilized gold and silver nanoclusters and their single crystal structures. Here the single crystal copper nanocluster species (Cu6(SC7H4NO)6) determined by X-ray crystallography and mass spectrometry is presented. The hexanuclear copper core is a distorted octahedron surrounded by six mercaptobenzoxazole ligands as protecting units through a simple bridging bonding motif. Density functional theory (DFT) calculations provide…

optical absorptionMaterials scienceGeneral Chemical EngineeringInorganic chemistryGeneral Physics and AstronomyMedicine (miscellaneous)chemistry.chemical_elementelectrochemical sensorkuparinanocluster02 engineering and technologyElectronic structure010402 general chemistry01 natural sciencesBiochemistry Genetics and Molecular Biology (miscellaneous)NanoclustersMetalCluster (physics)General Materials Scienceta116ta114Full PaperGeneral EngineeringFull Papers021001 nanoscience & nanotechnologyCopper0104 chemical sciencesCrystallographyOctahedronchemistryvisual_artcoppervisual_art.visual_art_mediumDensity functional theory0210 nano-technologysingle crystalSingle crystalAdvanced Science
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CCDC 1963049: Experimental Crystal Structure Determination

2019

Related Article: Xiaohui Gao, Shuijian He, Chunmei Zhang, Cheng Du, Xi Chen, Wei Xing, Shengli Chen, Andre Clayborne, Wei Chen|2016|Adv. Sci.|3|1600126|doi:10.1002/advs.201600126

hexakis(acetone)-sodium hexakis(mu-13-benzoxazole-2-thiolato)-hexa-copperSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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