0000000001319706

AUTHOR

Mário N. Berberan-santos

showing 2 related works from this author

Pt(II) and Pd(II)-assisted coupling of nitriles and 1,3-diiminoisoindoline : Synthesis and luminescence properties of (1,3,5,7,9-pentaazanona-1,3,6,8…

2017

Treatment of trans-[PtCl2(NCR)2] 1 (R = Me (1a), Et (1b), o-ClC6H4 (1c), p-ClC6H4 (1d), p-(HCdouble bond; length as m-dashO)C6H4 (1e), p-O2NC6H4CH2 (1f)) with 1,3-diiminoisoindoline HNdouble bond; length as m-dashCC6H4C(NH)double bond; length as m-dashNH 2 gives access to the corresponding (1,3,5,7,9-pentaazanona-1,3,6,8-tetraenato)Pt(II) complexes [PtCl{NHdouble bond; length as m-dashC(R)Ndouble bond; length as m-dashC(C6H4)NCdouble bond; length as m-dashNC(R)double bond; length as m-dashNH}] 3a–f, in good yields (65–70%). The reaction of trans-[PdCl2(NCMe)2] 4a with 2 furnishes (1,3,5,7,9-pentaazanona-1,3,6,8-tetraenato)Pd(II) complex [PdCl{NHdouble bond; length as m-dashC(Me)Ndouble bond…

kemiaStereochemistryhiili1Solid-state010402 general chemistrychemistry01 natural sciencesMedicinal chemistrynitrogenInorganic Chemistrychemistry.chemical_compoundpentaazanonatetraene complexestyppiMaterials ChemistryluminescencenitrilesPhysical and Theoretical Chemistryta116Dichloromethanemetal-assisted additions010405 organic chemistryluminesenssicarbonCoupling (probability)0104 chemical scienceschemistryYield (chemistry)13-diiminoisoindolinePolystyreneAbsorption (chemistry)Luminescence3-diiminoisoindolinePolyhedron
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CCDC 1518110: Experimental Crystal Structure Determination

2017

Related Article: Jamal Lasri, Bruno Pedras, Matti Haukka, Mário N. Berberan-Santos|2017|Polyhedron|133|195|doi:10.1016/j.poly.2017.05.036

Space GroupCrystallographyCrystal SystemCrystal Structurechloro-[NN'-(1H-isoindole-13(2H)-diylidene)bis(ethanimidamidato)]-platinum(ii)Cell ParametersExperimental 3D Coordinates
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