0000000001320358

AUTHOR

Andrew R. Frojd

showing 2 related works from this author

Au70S20(PPh3)12: an intermediate sized metalloid gold cluster stabilized by the Au4S4 ring motif and Au-PPh3 groups

2018

Reducing (Ph3P)AuSC(SiMe3)3 with L-Selectride® gives the medium-sized metalloid gold cluster Au70S20(PPh3)12. Computational studies show that the phosphine bound Au-atoms not only stabilize the electronic structure of Au70S20(PPh3)12, but also behave as electron acceptors leading to auride-like gold atoms on the exterior.

Inorganic chemistry02 engineering and technologyElectronic structure010402 general chemistryRing (chemistry)01 natural scienceskultaCatalysischemistry.chemical_compoundMaterials Chemistryta116chemistry.chemical_classificationGold clusterChemistryMetals and AlloysGeneral ChemistrygoldElectron acceptor021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyCeramics and CompositesnanohiukkasetnanoparticlesMetalloid0210 nano-technologyPhosphineChemical Communications
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CCDC 1575582: Experimental Crystal Structure Determination

2017

Related Article: Sebastian Kenzler, Claudio Schrenk, Andrew R. Frojd, Hannu Häkkinen, Andre Z. Clayborne, Andreas Schnepf|2018|Chem.Commun.|54|248|doi:10.1039/C7CC08014J

Space GroupCrystallographyCrystal Systemicosakis(mu-sulfido)-dodecakis(triphenylphosphine)-heptaconta-goldCrystal StructureCell ParametersExperimental 3D Coordinates
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