Author: Frédéric Schmitt

0000000001320683

AUTHOR

Frédéric Schmitt

Catalytic and anticancer activities of sawhorse-type diruthenium tetracarbonyl complexes derived from fluorinated fatty acids

The reaction of fluorinated fatty acids, perfluorobutyric acid (C3F7CO2H), and perfluorododecanoic acid (C11F23CO2H), with dodecacarbonyltriruthenium (Ru3(CO)12) under reflux in tetrahydrofuran, followed by addition of two-electron donors (L) such as pyridine, 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane, or triphenylphosphine, gives stable diruthenium complexes Ru2(CO)4(μ2-η2-O2CC3F7)2(L)2 (1a, L = C5H5N; 1b, L = PTA; 1c, L = PPh3) and Ru2(CO)4(μ2-η2-O2CC11F23)2(L)2 (2a, L = C5H5N; 2b, L = PTA; 2c, L = PPh3). The catalytic activity of the complexes for hydrogenation of styrene under supercritical carbon dioxide has been assessed and compared to the analogous triphenylphosphine complexes w…

research product

CCDC 914515: Experimental Crystal Structure Determination

Related Article: Justin P. Johnpeter, Laurent Plasseraud, Frédéric Schmitt, Lucienne Juillerat-Jeanneret, Bruno Therrien|2013|J.Coord.Chem.|66|1753|doi:10.1080/00958972.2013.790020

research product

CCDC 914514: Experimental Crystal Structure Determination

Related Article: Justin P. Johnpeter, Laurent Plasseraud, Frédéric Schmitt, Lucienne Juillerat-Jeanneret, Bruno Therrien|2013|J.Coord.Chem.|66|1753|doi:10.1080/00958972.2013.790020

research product

PEPhysical Sciences and Engineering
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LSLife Sciences
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