0000000001320744

AUTHOR

Jakob Steube

showing 3 related works from this author

Cover Feature: Excited‐State Kinetics of an Air‐Stable Cyclometalated Iron(II) Complex (Chem. Eur. J. 51/2019)

2019

Feature (computer vision)Chemical physicsChemistryExcited stateOrganic ChemistryKineticsCover (algebra)General ChemistryCatalysisChemistry – A European Journal
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Excited-State Kinetics of an Air-Stable Cyclometalated Iron(II) Complex.

2019

The complex class [Fe(N^N^C)(N^N^N)]+ with an Earth-abundant metal ion has been repeatedly suggested as a chromophore and potential photosensitizer on the basis of quantum chemical calculations. Synthesis and photophysical properties of the parent complex [Fe(pbpy)(tpy)]+ (Hpbpy=6-phenyl-2,2'-bipyridine and tpy=2,2':6',2''-terpyridine) of this new chromophore class are now reported. Ground-state characterization by X-ray diffraction, electrochemistry, spectroelectrochemistry, UV/Vis, and X-ray spectroscopy in combination with DFT calculations proves the high impact of the cyclometalating ligand on the electronic structure. The photophysical properties are significantly improved compared to …

010405 organic chemistryChemistryLigandOrganic ChemistryChemieGeneral ChemistryElectronic structureChromophore010402 general chemistryElectrochemistryPhotochemistry01 natural sciencesCatalysis0104 chemical scienceschemistry.chemical_compoundBipyridineExcited stateTriplet stateTerpyridineChemistry (Weinheim an der Bergstrasse, Germany)
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CCDC 1904835: Experimental Crystal Structure Determination

2020

Related Article: Jakob Steube, Lukas Burkhardt, Ayla Päpcke, Johannes Moll, Peter Zimmer, Roland Schoch, Christoph Wölper, Katja Heinze, Stefan Lochbrunner, Matthias Bauer|2019|Chem.-Eur.J.|25|11826|doi:10.1002/chem.201902488

[2-([22'-bipyridin]-6-yl)phenyl]-(22':6'2''-terpyridine)-iron tetraphenylborate dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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