0000000001320829

AUTHOR

Wafa Harhouri

showing 2 related works from this author

Synthesis, spectroscopic, cyclic voltammetry properties and molecular structure of the thiocyanato-N meso-tetratolylporphyrinato zinc(II) ion complex

2017

International audience; This paper describes the synthesis of the (thiocyanato-N)(meso-tetratolylporphyrinato)zinc(II) chlorobenzene monosolvate complex with the formula [K(2,2,2-crypt)][Zn(TTP)(NCS)]·C6H5Cl (I) using the cryptand-222 to solubilize potassium thiocyanate in chlorobenzene solvent. Complex (I) has been characterized by elementary analysis, IR, UV–vis, 1H NMR and MS, and the structure of this new zinc(II) metalloporphyrin been examined crystallographically. A cyclic voltammetry investigation was also carried out on this species. The title compound crystallizes in the triclinic, space group P-1, with a = 11.5151(7) Å, b = 15.212(10) Å, c = 20.1093(12) Å, α = 80.428(4)°, β = 74.9…

Cyclic voltammetryInorganic chemistrychemistry.chemical_elementZincTriclinic crystal system010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciences[ CHIM ] Chemical SciencesAnalytical ChemistryInorganic Chemistrychemistry.chemical_compoundPotassium thiocyanateUV–visible[CHIM]Chemical SciencesSpectroscopyOrganic ChemistryPorphyrinZinc porphyrin complex0104 chemical sciences3. Good healthX-ray diffractionCrystallographychemistryChlorobenzeneX-ray crystallographyProton NMRCyclic voltammetry
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CCDC 976101: Experimental Crystal Structure Determination

2016

Related Article: Zouhour Denden, Wafa Harhouri, Leila Ben Haj Hassen, Yoann Rousselin, Eric Saint-Aman, Habib Nasri|2017|J.Mol.Struct.|1133|472|doi:10.1016/j.molstruc.2016.11.080

Space GroupCrystallography(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium(i) (5101520-tetrakis(4-methylphenyl)porphyrinato)-isothiocyanato-zinc(ii) chlorobenzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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