Author: Johann Baraut

0000000001320996

AUTHOR

Johann Baraut

showing 3 related works from this author

Assessment of Catalysis by Arene‐Ruthenium Complexes Containing Phosphane or NHC Groups bearing Pendant Conjugated Diene Systems

2015

Two p-cymene-ruthenium complexes 1 and 2 were isolated in high yields by treating the [RuCl2(p-cymene)]2 dimer with new hybrid phosphane- or NHC-linked diene ligands. Both complexes were fully characterized by NMR spectroscopy, and the molecular structure of the ruthenium–p-cymene complex 1, containing the phosphane–diene ligand system, was determined by X-ray diffraction analysis. The catalytic activities of both compounds were probed in atom-transfer radical addition (ATRA) and polymerization (ATRP), in the cyclopropanation of olefins, in the ring-opening metathesis polymerization (ROMP) of norbornene, and in the synthesis of enol esters from hex-1-yne and 4-acetoxybenzoic acid.

Dienechemistry.chemical_elementHomogeneous catalysisROMPMetathesisEnolRutheniumInorganic Chemistrychemistry.chemical_compoundPolymerizationchemistryPolymer chemistryOrganic chemistryNorborneneEuropean Journal of Inorganic Chemistry

researchProduct

CCDC 1056295: Experimental Crystal Structure Determination

2015

Related Article: Johann Baraut, Alexandre Massard, Florian Chotard, Ewen Bodio, Michel Picquet, Philippe Richard, Yannick Borguet, François Nicks, Albert Demonceau, Pierre Le Gendre|2015|Eur.J.Inorg.Chem.||2671|doi:10.1002/ejic.201500054

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-(eta6-1-isopropyl-4-methylbenzene)-((4-methylhexyl)(diphenyl)phosphine)-ruthenium toluene solvateExperimental 3D Coordinates

researchProduct

CCDC 1023384: Experimental Crystal Structure Determination

2015

Related Article: Johann Baraut, Alexandre Massard, Florian Chotard, Ewen Bodio, Michel Picquet, Philippe Richard, Yannick Borguet, François Nicks, Albert Demonceau, Pierre Le Gendre|2015|Eur.J.Inorg.Chem.||2671|doi:10.1002/ejic.201500054

Space GroupCrystallographydichloro-(eta6-1-isopropyl-4-methylbenzene)-((4-methylenehex-5-en-1-yl)(diphenyl)phosphine)-rutheniumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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