0000000001321458

AUTHOR

Marcin Moskwa

showing 3 related works from this author

Structural phase transitions coupled with prominent dielectric anomalies and dielectric relaxation in [(CH3)3NH]2[KCo(CN)6] and mixed [(CH3)3NH]2[KFe…

2020

The crystals of pure [(CH3)3NH]2[KFe(CN)6] (TrMAFe) and [(CH3)3NH]2[KCo(CN)6] (TrMACo) as well as their mixed crystals (TrMAFexCo1−x), with different ratios of x = 0, 0.12, 0.18, 0.49, 0.56, 0.73, 0.81, 1.0, have been grown from aqueous solutions. The structure of TrMACo has been determined at 360 K to be cubic (Fmm). In phase II (100 K), the TrMACo crystal is monoclinic (C2/c). The thermal stability of the pure and mixed crystals has been determined by using both DTA and TGA. Based on the DSC results, we have found a single phase transition (PT) for both pure and mixed crystals. The Fe(III) concentration was estimated by using the SEM technique. We have found a linear relationship between …

Inorganic ChemistryCrystalMaterials sciencePhase (matter)Relaxation (NMR)Analytical chemistryDielectricActivation energyMole fractionMonoclinic crystal systemPhase diagramDalton Transactions
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CCDC 1965548: Experimental Crystal Structure Determination

2020

Related Article: Magdalena Rok, Bartosz Zarychta, Marcin Moskwa, Błażej Dziuk, Wojciech Medycki, Grażyna Bator|2020|Dalton Trans.|49|1830|doi:10.1039/C9DT04703D

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[bis(trimethylammonium) hexakis(mu-cyano)-cobalt(iii)-potassium(i)]
researchProduct

CCDC 1965549: Experimental Crystal Structure Determination

2020

Related Article: Magdalena Rok, Bartosz Zarychta, Marcin Moskwa, Błażej Dziuk, Wojciech Medycki, Grażyna Bator|2020|Dalton Trans.|49|1830|doi:10.1039/C9DT04703D

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[bis(trimethylammonium) hexakis(mu-cyano)-cobalt(iii)-potassium(i)]
researchProduct