6533b7cefe1ef96bd1257290
RESEARCH PRODUCT
Gold catalyzed stereoselective tandem hydroamination–formal aza-Diels–Alder reaction of propargylic amino esters
Carlos Del PozoMaría Sánchez-rosellóMiguel A. MaestroJavier MiróSantos FusteroJavier GonzalezPaula Bellosubject
Amino estersChemistryStereochemistryMetals and AlloysDiastereomerGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsStereocenterCatalysisIntramolecular forceMaterials ChemistryCeramics and CompositesStereoselectivityAza-Diels–Alder reactionHydroaminationdescription
A gold-catalyzed tandem intramolecular hydroamination-formal aza-Diels-Alder reaction of propargylic amino esters is described. The overall process leads to the formation of a tetracyclic framework as a single diastereoisomer, with the creation of four bonds and five stereocenters.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-01-11 | Chemical Communications |