6533b7cefe1ef96bd1257841

RESEARCH PRODUCT

Preparation of Polymer-Supported Polyazamacrocycles. The Role of the Polymeric Matrix in the Preparation of Polymer-Supported Polyazamacrocycles

Enrique García-españaM. I. BurgueteB. AltavaS. V. LuisJuan C. FríasJ. F. Miravet

subject

Methacrylate copolymerChemistryGeneral Chemical Engineeringtechnology industry and agriculturePolymeric matrixGeneral ChemistryIndustrial and Manufacturing EngineeringIonic selectivityMetalPolymerizationvisual_artPolymer chemistryvisual_art.visual_art_mediumIon-exchange resinSelectivityPolymer supported

description

Different approaches have been studied for the preparation of resins containing different polyazamacrocycles. Preparation of monolithic resins by polymerization of vinylic derivatives of the corresponding macrocycles is shown to be a more versatile strategy for this purpose. The use of energy-dispersive analysis by X-ray has revealed to be a very useful tool for the rapid evaluation of the interaction of those materials with both anions and cations and has allowed the corresponding selectivity trends to be obtained in a fast and simple way. Important effects of the polymeric matrix are observed in some cases.

https://doi.org/10.1021/ie000098q