6533b7cffe1ef96bd1258282

RESEARCH PRODUCT

ChemInform Abstract: Synthesis of Sesquiterpenes via Silicon-Guided Rearrangement of Epoxydecalins

Begoña GarcíaAna M. ColladoGonzalo BlayJosé R. Pedro

subject

TerpeneSiliconChemistryStereochemistryGroup (periodic table)chemistry.chemical_elementGeneral MedicineCarbocation

description

A survey of the rearrangement of methyldecalins via C-5 carbocation intermediates, with special attention to the silicon-guided rearrangement of epoxydecalins is provided. A TMS group properly posi...

https://doi.org/10.1002/chin.200915258