6533b7cffe1ef96bd12585a7

RESEARCH PRODUCT

Incommensurate nature of the multilayered molecular ferromagnetic metals based on bis(ethylenedithio)tetrathiafulvalene and bimetallic oxalate complexes.

José Ramón Galán-mascarósSander Van SmaalenEugenia Martínez-ferreroCarlos J. Gómez-garcíaEugenio Coronado

subject

ChemistryMineralogyOxalateInorganic ChemistryMetalParamagnetismchemistry.chemical_compoundCrystallographyFerromagnetismElectrical resistivity and conductivityvisual_artvisual_art.visual_art_mediumPhysical and Theoretical ChemistryIsostructuralBimetallic stripTetrathiafulvalene

description

The salt [ET]x[MnRh(ox)(3)].CH(2)Cl(2) (x = 2.526(1)) has been obtained and characterized. This paramagnetic metal is essentially isostructural to the ferromagnetic metal [ET]y[MnCr(ox)(3)].CH(2)Cl(2) (y approximately equal to 3) and provides a definite answer on the origin of the structural disorder present on such systems. As in the ferromagnetic analogue, this material shows high electrical conductivity at room temperature (13 S.cm(-1)) and metallic behavior.

yearjournalcountryeditionlanguage
2004-08-03Inorganic chemistry
10.1021/ic049424ahttps://pubmed.ncbi.nlm.nih.gov/15285651