6533b7cffe1ef96bd125864d
RESEARCH PRODUCT
Grand canonical rate theory for electrochemical and electrocatalytic systems I: General formulation and proton-coupled electron transfer reactions
Marko Melandersubject
Materials science010304 chemical physicsProtonRenewable Energy Sustainability and the EnvironmentElectrochemical kineticsElectron010402 general chemistryCondensed Matter PhysicsElectrocatalystElectrochemistry01 natural sciences0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysisElectron transferChemical physics0103 physical sciencesMaterials ChemistryElectrochemistryProton-coupled electron transferAdiabatic processNuclear ExperimentQuantumdescription
A generally valid rate theory at fixed potentials is developed to treat electrochemical and electrocatalytic potential-dependent electron, proton, and proton-coupled electron reactions. Both classical and quantum reactions in adiabatic and non-adiabatic limits are treated. The applicability and new information obtained from the theory is demonstrated for the gold catalyzed acidic Volmer reaction.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2020-06-12 |