6533b7cffe1ef96bd12586ae
RESEARCH PRODUCT
Communication: anion-specific response of mesoscopic organization in ionic liquids upon pressurization
Fabrizio Lo CelsoAlessandro TrioloLorenzo GontraniOlga Russinasubject
Materials scienceneutron x-raycomputational studiesGeneral Physics and Astronomy010402 general chemistrystructural scale01 natural sciencesIonionic liquidsPhysics and Astronomy (all)chemistry.chemical_compoundCabin pressurizationSettore CHIM/02Mesoscopic spatial scalesionic liquidspressurisationmolecular dynamics0103 physical sciencesFadingPhysical and Theoretical Chemistrystructural organization; ionic liquids; structural scale; computational studies; mesoscopic organizationMesoscopic physicsStructural organization010304 chemical physicsstructural organization0104 chemical scienceschemistryChemical physicsFeature (computer vision)mesoscopic organizationIonic liquiddescription
One of the outstanding features of ionic liquids is their inherently hierarchical structural organization at mesoscopic spatial scales. Recently experimental and computational studies showed the fading of this feature when pressurising. Here we use simulations to show that this effect is not general: appropriate anion choice leads to an obstinate resistance against pressurization. Published by AIP Publishing.
year | journal | country | edition | language |
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2018-01-01 |