Synthesis, X‐ray Studies and Magnetic Properties of Dinuclear Ni II and Cu II Complexes Bridged by the Azo‐2,2′‐bipyridine Ligand

6533b7cffe1ef96bd1258c7c

RESEARCH PRODUCT

Synthesis, X‐ray Studies and Magnetic Properties of Dinuclear Ni II and Cu II Complexes Bridged by the Azo‐2,2′‐bipyridine Ligand

José Ramón Galán-mascarós Cristian S. Campos-fernández Bradley W. Smucker Kim R. Dunbar

subject

Stereochemistry Chemistry Ligand chemistry.chemical_element Bridging ligand Triclinic crystal system Magnetic susceptibility 2 2'-Bipyridine Inorganic Chemistry Crystallography Paramagnetism Nickel chemistry.chemical_compound Transition metal

description

Two new paramagnetic transition metal complexes that contain the bridging ligand azo-2,2-bipyridine (abpy) have been prepared and characterized by X-ray crystallography and magnetic susceptibility measurements. The compound [Ni2(µ-abpy)(CH3CN)2(NO3)4]·2CH3CN (1·2CH3CN) crystallizes in the triclinic space group P1 ¯ with a = 8.290(5) A u , b = 8.343(5) A u , c = 11.180(5) A u , α = 105.36(3)°, β = 94.39(3)°, γ = 107.56(3)°, V = 700.5(7) A u 3 and Z = 1. The related salt [Cu2(µ

year	journal	country	edition	language
2003-02-18	European Journal of Inorganic Chemistry

https://doi.org/10.1002/ejic.200390131

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