6533b7cffe1ef96bd1258d91
RESEARCH PRODUCT
Cyclic Dinuclear Organotin Cations Stabilized by Bulky Substituents
Michael WagnerChristina DietzKlaus JurkschatDieter SchollmeyerBernhard Zobelsubject
Inorganic ChemistrySteric effectschemistry.chemical_compoundChemistryPropaneElectrospray ionizationOrganic ChemistryOrganic chemistryInfrared spectroscopyPhysical and Theoretical ChemistryMedicinal chemistrydescription
The syntheses of sterically congested 2,2-bis(diorganochloridostannyl)propane, Me2C(SnClR2)2 (1; R = CH(SiMe3)2), the related salts [cyclo-{Me2C(SnR2)2X}B(ArF)4] (2, X = Cl; 3, X = OAc; 4, X = OH; ArF = 3,5-(CF3)2C6H3), and the four-membered-ring cyclo-{Me2C(SnR2)2O} (5) are reported. The compounds have been characterized by elemental and EDX analyses, 1H, 11B, 13C, 19F, 29Si, and 119Sn NMR and IR spectroscopy, electrospray ionization mass spectrometry, and single-crystal X-ray diffraction analysis.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-11-19 | Organometallics |