6533b7cffe1ef96bd12591ec
RESEARCH PRODUCT
Iron(III) chloride as mild catalyst for the dearomatizing cyclization of N-acylindoles
Jingyu ZhangJing LiJas S WardKhai-nghi TruongKari RissanenMarkus Albrechtsubject
katalyytitkemialliset yhdisteetkatalyysiorgaaninen kemiaindoliinidescription
A catalytic approach for the preparation of indolines by dearomatizing cyclization is presented. FeCl3 acts as a catalyst to afford tetracyclic 5a,6-dihydro-12H-indolo[2,1-b][1,3]benzoxazin-12-ones in good yields. The cyclization also proceeds with tosylamides forming C-N bonds in 53 % yield. peerReviewed
year | journal | country | edition | language |
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2020-01-01 |