ChemInform Abstract: Switchable Palladium-Catalyst Reaction of Bromomethyl Sulfoxides, CO, and N-Nucleophiles: Aminocarbonylation at Csp3versus Oxidative Carbonylation of Amines.

6533b7cffe1ef96bd125980f

RESEARCH PRODUCT

ChemInform Abstract: Switchable Palladium-Catalyst Reaction of Bromomethyl Sulfoxides, CO, and N-Nucleophiles: Aminocarbonylation at Csp3versus Oxidative Carbonylation of Amines.

Cristian Mollar Carmen Ramírez De Arellano Gregorio Asensio Mercedes Medio-simón

subject

Coupling (electronics)chemistry.chemical_compound Nucleophile Chemistry Oxidative carbonylation Polymer chemistry General Medicine Palladium catalyst Pyrrole derivatives Carbon monoxide

description

Pd2(dba)3/ Xantphos-catalyzed coupling of the sulfoxides (I) and (V) with amines and carbon monoxide allows a new and efficient access to amides of type (IV) and (VI).

year	journal	country	edition	language
2013-02-26	ChemInform

https://doi.org/10.1002/chin.201309046

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