6533b7d0fe1ef96bd125a194

RESEARCH PRODUCT

Study of vacancy defects in PbSe and Pb1-xSnxSe by positron annihilation

V. P. ZlomanovV. StanovA. ChatchaturovS. MäkinenA. PolityReinhard Krause-rehberg

subject

Inorganic ChemistryNuclear physicsPositronChemistryVapor pressureAnnealing (metallurgy)Vacancy defectMaterials ChemistryCondensed Matter PhysicsPositron trappingMolecular physicsPositron annihilation

description

Abstract Positron lifetime measurements have been performed to study vacancy defects in vapour-liquid-solid (VLS) grown PbSe and Pb 1- x Sn x Se ( x = 0.07, 0.1, 0.3). Post-growth annealing under various vapour pressure conditions has been used to change the number of Pb vacancies, resulting in the determination of the specific positron trapping rate μ Pb v = (1.0±0.1)×10 14 s -1 . The sensitivity range of the positron annihilation method to the Pb vacancies was found to be 10 17 Pb ] 20 cm -3 . Positron lifetimes in perfect PbTe, PbSe and PbS crystals have been calculated. Moreover, we have predicted lifetimes of positrons trapped by vacancies. The calculated lifetimes in bulk and defects correspond well to the experimentally determined values.

https://doi.org/10.1016/0022-0248(93)90423-t