6533b7d0fe1ef96bd125a1b1
RESEARCH PRODUCT
Redox-active crown ethers derived from biphenyl. Electrochemical and spectroscopic study of binding processes with alkali, alkali-earth and mercury salts
Luis E. OchandoRamón Martínez-máñezCecilia AndreuJuan SotoJosém. AmigóAna M. Costerosubject
Biphenylchemistry.chemical_classificationConformational changeAlkaline earth metalChemistryOrganic ChemistryInorganic chemistrychemistry.chemical_elementAlkali metalElectrochemistryBiochemistryMercury (element)chemistry.chemical_compoundDrug DiscoveryMoietyCrown etherdescription
Abstract Three new electroactive ligands, 3a, 3b and 3c, that contain the biphenyl frameworks in their structure were prepared. These new ligands presented three interesting characteristics: 1) they exhibited a reversible oxidation, 2) the oxidation induced a conformational change in the crown moiety and 3) they had two different coordination centers, the crown ether and the dimethylamino groups. Electrochemical and spectroscopic studies using alkali, alkali-earth and mercury salts were carried out.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1998-07-01 | Tetrahedron |