6533b7d0fe1ef96bd125a5e9
RESEARCH PRODUCT
Cooperative supramolecular polymerization and amplification of chirality in C3-symmetrical OPE-based trisamides.
Fátima GarcíaEnrique OrtíE. MatesanzLuis SánchezPedro M. Viruelasubject
chemistry.chemical_classificationModels MolecularMolecular StructureOrganic ChemistrySupramolecular chemistryStereoisomerismGeneral ChemistryAmidesCatalysisPolymerizationSupramolecular polymersCrystallographychemistryPolymerizationRacemic mixtureSelf-assemblyChirality (chemistry)description
Sergeants-and-soldiers experiments demonstrate the amplification of chirality that transforms the racemic mixture of helical columns formed from OPE-based trisamides into enantiomerically enriched helical structures (see scheme).The cooperative supramolecular polymerization of the trisamides is investigated by theoretical calculations and temperature-dependent UV/Vis and CD experiments. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-05-26 | Chemistry (Weinheim an der Bergstrasse, Germany) |