6533b7d0fe1ef96bd125ac6f
RESEARCH PRODUCT
Volumetric and Acoustic Properties of Aqueous Solutions of Trifluoromethanesulfonate-Based Ionic Liquids at Several Temperatures
A. Vicent OrchillésErnesto VercherFrancisco J. LlopisPablo J. MiguelAntoni Martínez-andreusubject
MolarIsentropic compressibilitychemistry.chemical_compoundWork (thermodynamics)Molar volumeAqueous solutionIsentropic processChemistryGeneral Chemical EngineeringIonic liquidThermodynamicsGeneral ChemistryTrifluoromethanesulfonatedescription
In this work, densities and sound velocities of three ionic liquids, 3-butyl-1-ethylimidazolium trifluoromethanesulfonate, 3-butyl-1-methylimidazolium trifluoromethanesulfonate, and 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate, and their binary mixtures with water have been obtained at p = (101 ± 2) kPa and T = (278.15 to 338.15) K, covering the whole range of concentration. The isentropic compressibility and molar isentropic compression of pure components and mixtures have been calculated using the Newton–Laplace equation. Moreover, the excess molar volume and excess molar isentropic compression of mixtures have been then determined, and they have been fitted to temperature and composition by an extended Redlich–Kister equation. Optimal fitting parameters have been reported.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-06-28 | Journal of Chemical & Engineering Data |