6533b7d0fe1ef96bd125ac98

RESEARCH PRODUCT

Euonymus maackii Rupr. Seed oil as a new potential non-edible feedstock for biodiesel

Yao MengQi CuiThomas EfferthMing-zhu GaoYu-jie FuYu-jie FuYu-fei KangJu-zhao Liu

subject

Biodiesel060102 archaeologyRenewable Energy Sustainability and the Environment020209 energyLinoleic acidEN 1421406 humanities and the arts02 engineering and technologyPalmitic acidchemistry.chemical_compoundOleic acidchemistryBiodiesel production0202 electrical engineering electronic engineering information engineeringPalmitoleic acid0601 history and archaeologyFood scienceStearic acid

description

Abstract In this study, Euonymus maackii Seed oil (EMSO) was exploited and evaluated for the first time as a new non-edible oil feedstock for preparation of biodiesel. The EMSO yield was 41.06 ± 2.68 wt%. The fatty acid compositions of EMSO involved palmitoleic acid (2.01%), palmitic acid (14.5%), stearic acid (3.1%), oleic acid (49.8%), linoleic acid (29.3%), 11-Eicosenoic acid (0.1%) and arachidic acid (0.07%). Microwave-assisted transesterification with methanol provided a high conversion yield in short duration under low temperature. The 2.0 wt% of catalyst amount, 10:1 of methanol/oil molar ratio, 40 min of reaction time and 60 °C of temperature were found to be the optimum process conditions for the maximum biodiesel yield of 94.74 ± 2.09%. Using pseudo first-order kinetic model, the reaction rate constants were 2.145 × 102, 3.550 × 102 and 6.447 × 102 min−1 for 40, 50 and 60 °C, respectively. The thermodynamic property for biodiesel preparation was determined as activation energy = 47.67 kJ/mol. The fuel properties of the biodiesel product were evaluated and comparable to ASTM D-6751 and EN 14214 standards. Overall, this study revealed and confirmed the potential of Euonymus maackii seed oil as the appropriate alternative feedstock for biodiesel production.

https://doi.org/10.1016/j.renene.2018.10.035