Badanie metodą inwersyjnej chromatografii gazowej wpływu wielkości podstawnika na właściwości inkluzyjne kaliksarenów

6533b7d0fe1ef96bd125b087

RESEARCH PRODUCT

Badanie metodą inwersyjnej chromatografii gazowej wpływu wielkości podstawnika na właściwości inkluzyjne kaliksarenów

subject

calixarenes kaliksareny inverse gas chromatography kompleksy inkluzyjne właściwa objętość retencji specific retention volume inclusion complexes inwersyjna chromatografia gazowa

description

Badano wpływ wielkości alifatycznego podstawnika na zdolności inkluzyjne kaliksarenów {kaliks[4]arenu(K4), p-izopropylokaliks[4]arenu (IPK4) i p-tert-butylokaliks[4]arenu (TBK4)}. Oceny wpływu dokonywano za pomocą metody QSRR przy użyciu inwersyjnej chromatografii gazowej. W charakterze solutów użyto szeregu alifatycznych alkoholi, homologów benzenu i homologów pirydyny. Na podstawie indeksów retencji Kovatsa i wykresów zależności właściwej objętości retencji od temperatury wrzenia [Vg=f(Tw)] stwierdzono, że tylko podstawione kaliksareny wykazują właściwości inkluzyjne w stosunku do niższych alkoholi.

year	journal	country	edition	language
2009-01-01	Polimery

http://www.ichp.pl/polimery-bialon-hetper-metoda-inwersyjnej-chromatografii-

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