6533b7d0fe1ef96bd125b67d
RESEARCH PRODUCT
Chemistry of ?-hydridobis[pentacarbonylchromium(0)] species. Part III. Redox reactions with mercury(II) compounds and iodine
Maria Domenica Grillonesubject
HydrideInorganic chemistryMetals and Alloyschemistry.chemical_elementIodineMedicinal chemistryRedoxMercury (element)CatalysisInorganic ChemistryPart iiichemistry.chemical_compoundchemistryMaterials ChemistryAcetoneOrganometallic chemistrydescription
[Cr2(CO)10(μ-H)]− undergoes ready hydride substitution on reaction with HgX2 (X = Cl, Br, I or SCN) or with iodine in acetone, yielding [Cr2(CO)10(μ-X)]− complex species which can be converted quantitatively into [Cr(CO)5X]− anions by reactions conducted in the presence of an excess of X−.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1981-04-01 | Transition Metal Chemistry |