6533b7d0fe1ef96bd125b6b0

RESEARCH PRODUCT

Selective derivatisation of resorcarenes. Part 5. Acylation of tetrabenzoxazine derivatives

Walter VogtVolker BöhmerChristian SchmidtErich F. Paulus

subject

AcylationAcetic anhydridechemistry.chemical_compoundStructure analysischemistryMaterials ChemistryProton NMROrganic chemistryGeneral ChemistrySingle crystalCatalysis

description

The reaction of the tetrabenzoxazines 2 with acetic anhydride under mild conditions leads selectively and exclusively to the tetraamides 3 in which the oxazine rings are opened; their structure was deduced from their 1H NMR spectra and confirmed for one example by an X-ray single crystal structure analysis; acylation of the hydroxy groups was not observed.

https://doi.org/10.1039/a907622k