6533b7d1fe1ef96bd125c058
RESEARCH PRODUCT
Vapor–liquid equilibrium of binary mixtures of trichloroethylene with 1-pentanol, 2-methyl-1-butanol and 3-methyl-1-butanol at 100 kPa
Francisco J. LlopisPablo J. MiguelVicenta González-alfaroM. Isabel VázquezAna Dejozsubject
UNIQUACChromatographyChemistryGeneral Chemical EngineeringButanolGeneral Physics and AstronomyThermodynamicsMole fractionGroup contribution methodchemistry.chemical_compoundAzeotropeNon-random two-liquid modelVapor–liquid equilibriumBinary systemPhysical and Theoretical Chemistrydescription
Abstract Isobaric vapor–liquid equilibria (VLE) have been obtained for the systems trichloroethylene+1-pentanol, trichloroethylene+2-methyl-1-butanol and trichloroethylene+3-methyl-1-butanol at 100 kPa using a dynamic still. The experimental error in temperature is ±0.1 K, in pressure ±0.1 kPa, and in the liquid and vapor mole fraction ±0.001. The three systems satisfy the point-to-point thermodynamic consistency test. All the systems show positive deviations from ideality. The data have been correlated with the Margules, van Laar, Wilson, NRTL and UNIQUAC equations.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-02-01 | Fluid Phase Equilibria |