6533b7d1fe1ef96bd125c467

RESEARCH PRODUCT

Ionic circuitry with nanofluidic diodes

Patricio RamirezSalvador MafeSaima NasirWolfgang EnsingerJavier CerveraMubarak Ali

subject

Materials sciencebusiness.industryIonic bonding02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesPolyelectrolyte0104 chemical sciencesNanoporeMembraneOptoelectronicsElectronicsSurface charge0210 nano-technologybusinessDiodeElectronic circuit

description

Ionic circuits composed of nanopores functionalized with polyelectrolyte chains can operate in aqueous solutions, thus allowing the control of electrical signals and information processing in physiological environments. We demonstrate experimentally and theoretically that different orientations of single-pore membranes with the same and opposite surface charges can operate reliably in series, parallel, and mixed series-parallel arrangements of two, three, and four nanofluidic diodes using schemes similar to those of solid-state electronics. We consider also different experimental procedures to externally tune the fixed charges of the molecular chains functionalized on the pore surface, showing that single-pore membranes can be used efficiently in ionic circuitry with distinct ionic environments.

https://doi.org/10.1039/c9sm01654f