6533b7d1fe1ef96bd125ca75

RESEARCH PRODUCT

Acyclic imidoselenium(ii) dihalides: synthesis and X-ray structures of ClSe[N(But)Se]nCl (n = 1, 2)

Risto S. LaitinenTiina MaaninenElina WegeliusTristram Chivers

subject

CrystallographyChemistryStereochemistryMaterials ChemistryMetals and AlloysCeramics and CompositesX-rayGeneral ChemistryRing (chemistry)CatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materials

description

The reaction of SeCl2 with tert-butylamine in THF yields the acyclic imidoselenium(II) dichlorides ClSeN(But)NSeCl and ClSeN(But)SeN(But)SeCl, in addition to the six-membered ring Se3(NBut)3.

https://doi.org/10.1039/b001002m