6533b7d1fe1ef96bd125d820
RESEARCH PRODUCT
Synthesis of small carboranylsilane dendrons as scaffolds for multiple functionalizations.
Arántzazu González-campoReijo SillanpääC. ViñasRosario NúñezRaikko KivekäsAnna LaromaineF. Teixidorsubject
chemistry.chemical_compoundChemistryHydrosilylationOrganic ChemistryCarboraneOrganic chemistrySurface modificationSequence (biology)Physical and Theoretical ChemistryBiochemistryCombinatorial chemistryStyrenedescription
Small carbosilane dendrons in which a closo-carborane is located at the focal point have been prepared by a sequence of steps involving hydrosilylation and reduction reactions. These compounds are used as scaffolds for peripheral functionalization with styrene, chlorovinylstyrene, or suitable carboranes, while keeping the C(cluster)-Si (C(c)-Si) bond. Modification of the core by reduction of the carborane with Mg/BrCH2CH2Br was also achieved.
year | journal | country | edition | language |
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2006-09-01 | Organic letters |