6533b7d2fe1ef96bd125e906

RESEARCH PRODUCT

Melamine induced conformational change of ethyl resorcinarene in solid state

Dezsö FalábuKari RissanenElina WegeliusMaija Nissinen

subject

Conformational changeChemistryHydrogen bonded networkHydrogen bondSolid-stateGeneral ChemistryResorcinareneCondensed Matter PhysicsPhotochemistrychemistry.chemical_compoundIntramolecular forcePolymer chemistryGeneral Materials ScienceMelamine

description

When ethyl resorcinarene (1) and melamine (2) are co-crystallised, all intramolecular hydrogen bonds keeping the resorcinarene in crown conformation are broken causing an unexpected conformational change to boat, and a highly ordered hydrogen bonded network is formed.

https://doi.org/10.1039/b006193j