6533b7d2fe1ef96bd125e964

RESEARCH PRODUCT

Indications of Two Separate Relaxators in the Subphonon Region of Tetragonal BaTiO 3

Marc D. FontanaM. MaglioneK. A. MüllerB. JannotK. Laabidi

subject

PermittivityRange (particle radiation)Materials scienceCondensed matter physicsbusiness.industryRelaxation (NMR)General Physics and AstronomyDielectricLight scatteringlaw.inventionCondensed Matter::Materials ScienceTetragonal crystal systemsymbols.namesakeOpticslawsymbolsbusinessRaman spectroscopyElectron paramagnetic resonance

description

Significant discrepancies were generally reported in the dynamics of BaTiO3 between results deduced from various experimental techniques. Here dielectric and quasi-elastic light scattering measurements are investigated on high-quality BaTiO3 crystals. We show that two relaxators have to be introduced below the soft-phonon frequency. A complete dielectric dispersion in a very wide frequency range is thus achieved which consistently relies the high-frequency dielectric results and the Raman data. There is also a qualitative agreement between our two-relaxator model and the dynamics which were deduced some time ago from EPR experiments.

https://doi.org/10.1209/0295-5075/26/4/012