6533b7d2fe1ef96bd125f35b

RESEARCH PRODUCT

Linked amido-indenyl complexes of titanium

Francisco AmorJun Okuda

subject

LigandOrganic Chemistrychemistry.chemical_elementAlkylationBiochemistryMedicinal chemistryInorganic ChemistryDilithiumchemistry.chemical_compoundchemistryMaterials ChemistryOrganic chemistryPhysical and Theoretical ChemistryDerivative (chemistry)Titanium

description

Abstract Titanium complexes Ti( η 5 : η 1 -C 9 H 6 SiMe 2 NCMe 3 )X 2 (X = Cl, Me, CH 2 SiMe 3 , CH 2 Ph) containing the tert -amino-functionalized indenyl ligand C 9 H 6 SiMe 3 NCMe 3 have been synthesized by the reaction of the dilithium derivative Li 2 [C 9 H 6 SiMe 2 NCMe 3 ] with TiCl 3 (THF) 3 followed by oxidation or by the alkylation of the dichloro derivative. Unexpectedly, the reaction of C 9 H 6 (SiMe 3 )(SiMe 2 Cl) with TiCl 4 does not give Ti( η 5 -C 9 H 6 SiMe 2 Cl)Cl 3 .

yearjournalcountryeditionlanguage
1996-08-01Journal of Organometallic Chemistry
https://doi.org/10.1016/0022-328x(96)06350-4