6533b7d3fe1ef96bd125fe12
RESEARCH PRODUCT
Valence electronic structure of polystyrenes with different tacticities : how to go (or not to go) too far ? A joint theoretical and experimental approach
Enrique OrtíJean-luc BrédasN. IshiharaJean-jacques Pireauxsubject
RadiationValence (chemistry)ChemistryComputationElectronic structureCondensed Matter PhysicsAtomic and Molecular Physics and OpticsSpectral lineElectronic Optical and Magnetic Materialssymbols.namesakeX-ray photoelectron spectroscopysymbolsPhysical and Theoretical ChemistryAtomic physicsHamiltonian (quantum mechanics)Spectroscopydescription
Abstract Monochromadzed Al-K α XPS spectra from iso- and syndiotacdc polystyrenes are analyzed with the help of theoretical band structures and densities of states produced from a valence effective Hamiltonian (VEH) computation scheme. A discussion of the correlations found between the experimental and theoretical results points out to the potentialities but also to the limits of both methods.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1990-01-01 | Journal of Electron Spectroscopy and Related Phenomena |