6533b7d3fe1ef96bd125fed3

RESEARCH PRODUCT

Structure and Thermodynamics of Binary Mixtures (Solutions)

Walter Schirmacher

subject

Condensed Matter::Soft Condensed MatterPhysicssymbols.namesakesymbolsRegular solutionStructure (category theory)Binary numberThermodynamicsGibbs free energyPhase diagram

description

The concepts of chapter 2 are generalized to binary liquid mixtures (solutions). With the help of the concept of number and concentration fluctuations contact to the thermodynamics of solutions and physical chemistry of solutions is made. The perturbative RPA is shown to be equivalent to Flory’s theory of regular solutions. The phase diagrams of regular solutions and metal-salt solutions are discussed and explained in terms of the theories.

https://doi.org/10.1007/978-3-319-06950-0_3