6533b7d3fe1ef96bd125ff38

RESEARCH PRODUCT

Unusual Magnetic Behavior in the Layered Ferromagnet [Ni(C6H14N2)2]3[Fe(CN)6]2·2H2O

Eugenio CoronadoMiguel Clemente-leónJosé Ramón Galán-mascarósFrancisco J. RomeroFrederic BellouardKim R. DunbarCarlos J. Gómez-garcía

subject

Inorganic ChemistryMagnetizationNickelNuclear magnetic resonanceCondensed matter physicsMolecular magnetschemistryFerromagnetismchemistry.chemical_elementCoercivityMagnetic susceptibility

description

The cyano-bridged molecular complex [Ni(C6H14N2)2]3[Fe(CN)6]2·2H2O, with a rectangular 2D structure, displays long-range ferromagnetic ordering at 14 K, and exhibits unusual magnetic properties for this type of material, as confirmed by the appearance of two different peaks in the AC magnetic susceptibility plot, and a high coercive field (2.3 kOe) and remnant magnetization (6.8 μB). (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)

https://doi.org/10.1002/1099-0682(200207)2002:7<1603::aid-ejic1603>3.0.co;2-t