One-pot electrocatalytic oxidation of glycerol to DHA

6533b7d3fe1ef96bd125ffe6

RESEARCH PRODUCT

One-pot electrocatalytic oxidation of glycerol to DHA

Rosaria Ciriminna Giovanni Palmisano Cristina Della Pina Michele Rossi Mario Pagliaro

subject

chemistry.chemical_compound chemistry Organic Chemistry Drug Discovery Glycerol Organic chemistry Hydroxypyruvic acid Biochemistry

description

Abstract One-pot, waste-free oxidation of glycerol to 1,3-dihydroxyacetone (DHA) was achieved by simply applying a small electric potential (1.1 V vs Ag/AgCl) to a glycerol solution in water buffered at pH 9.1 in the presence of 15 mol % TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl). Prolonging the reaction time affords comparable amounts of hydroxypyruvic acid.

year	journal	country	edition	language
2006-09-01

http://hdl.handle.net/10447/4665

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