6533b7d3fe1ef96bd1260119

RESEARCH PRODUCT

Synthesis, crystal structure and magnetic properties of an oxalato-bridged Re(IV)Mo(VI) heterobimetallic complex.

Miguel JulveGiovanni De MunnoDonatella ArmentanoFrancesc LloretJuan FausJosé Martínez-lilloJosé Martínez-lillo

subject

Inorganic Chemistrychemistry.chemical_classificationCrystallographychemistryMolybdenumchemistry.chemical_elementCrystal structureCoordination complex

description

The Re(IV)-Mo(VI) compound of formula (PPh(4))(2)[ReCl(4)(μ-ox)MoO(2)Cl(2)] (1) constitutes the first example of a heterodinuclear oxalato-bridged complex in the coordination chemistry of molybdenum.

10.1039/c0dt01323dhttps://pubmed.ncbi.nlm.nih.gov/21180753